LaMgAl11O19 synthesis using non-hydrolytic sol-gel methods

Polycrystalline LaMgAl₁₁O₁₉ (LMA) was prepared by four different non-hydrolytic sol-gel methods. From stable solutions, four powder precursors containing an amorphous and nanocrystalline phase with specific reactivity were obtained. The particle size, morphology, thermal behaviour, and phase composition of the powder precursors were studied using DLS, TEM, DSC/TG and XRD. Bulk ceramic samples containing LMA were prepared at 1200?°C for 16?h and examined in terms of phase purity and microstructure using XRD, SEM, and TEM. Raman spectroscopy of pure LMA was used to study the structure in detail. A mechanism of LMA formation and a relation between powder precursor properties and final phase composition is proposed. These findings may be useful for designing modern technologies for fabrication of LMA for optical or protective coating applications.     

Porous polyurethane film fabricated via the breath figure approach for sustained drug release

The breath figure (BF) method is an effective process for fabricating porous polymeric films. In this study, we fabricated porous polymer films from thermoplastic polyurethane (PU) through static BF with CHCl₃ as a solvent under 55–80% relative humidity. The porous PU films were prepared within various pore structures and sizes, which were adjustable, depending on the fabrication conditions. The humidity and exposure time were examined as variable parameters affecting the surface morphology, wettability, and cytotoxicity. Atorvastatin calcium, a hyperlipidemic agent, was loaded into the porous films during the casting process, and the drug-loading and drug-releasing behaviors of the porous PU membranes were evaluated. Approximately 60–80% of the drug was released in 14 days. The films exhibited sustained drug-release performances because of the hydrophobicity and nonbiodegradable nature of PU for perivascular drug administration. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47658.     

Scanning Probe Lithography Patterning of Monolayer Semiconductors and Application in Quantifying Edge Recombination

Scanning probe lithography is used to directly pattern monolayer transition metal dichalcogenides (TMDs) without the use of a sacrificial resist. Using an atomic‐force microscope, a negatively biased tip is brought close to the TMD surface. By inducing a water bridge between the tip and the TMD surface, controllable oxidation is achieved at the sub‐100 nm resolution. The oxidized flake is then submerged into water for selective oxide removal which leads to controllable patterning. In addition, by changing the oxidation time, thickness tunable patterning of multilayer TMDs is demonstrated. This resist‐less process results in exposed edges, overcoming a barrier in traditional resist‐based lithography and dry etch where polymeric byproduct layers are often formed at the edges. By patterning monolayers into geometric patterns of different dimensions and measuring the effective carrier lifetime, the non‐radiative recombination velocity due to edge defects is extracted. Using this patterning technique, it is shown that selenide TMDs exhibit lower edge recombination velocity as compared to sulfide TMDs. The utility of scanning probe lithography towards understanding material‐dependent edge recombination losses without significantly normalizing edge behaviors due to heavy defect generation, while allowing for eventual exploration of edge passivation schemes is highlighted, which is of profound interest for nanoscale electronics and optoelectronics.     

Living Materials Herald a New Era in Soft Robotics

Living beings have an unsurpassed range of ways to manipulate objects and interact with them. They can make autonomous decisions and can heal themselves. So far, a conventional robot cannot mimic this complexity even remotely. Classical robots are often used to help with lifting and gripping and thus to alleviate the effects of menial tasks. Sensors can render robots responsive, and artificial intelligence aims at enabling autonomous responses. Inanimate soft robots are a step in this direction, but it will only be in combination with living systems that full complexity will be achievable. The field of biohybrid soft robotics provides entirely new concepts to address current challenges, for example the ability to self‐heal, enable a soft touch, or to show situational versatility. Therefore, “living materials” are at the heart of this review. Similarly to biological taxonomy, there is a recent effort for taxonomy of biohybrid soft robotics. Here, an expansion is proposed to take into account not only function and origin of biohybrid soft robotic components, but also the materials. This materials taxonomy key demonstrates visually that materials science will drive the development of the field of soft biohybrid robotics.     

共价有机框架材料及其在关键核素分离中的应用进展

共价有机框架材料（COFs）是一类由共价键连接的多孔晶态材料。因具有单体链接方式灵活、结构可调、活性位点丰富、比表面积大、理化性质相对稳定等特点，它们在气体储存与分离、能量储存、催化和光电学领域受到了广泛的关注。本文主要从结构设计、合成方法及功能化、材料的分析表征和晶形控制等方面概括地介绍了COFs材料。在此基础上，综述了COFs材料在关键核素分离方面的研究进展，并展望了其在核素分离领域的应用前景和今后的研究方向。     

Adsorption studies of Pb (II) by two different magnetic MnFe2O4 materials synthesized with sol-gel process

Abstract

The spherical nanomaterials of MnFe-Ac and MnFe-Na can be synthesized with sol-gel method. The adsorption test of Pb (II) was carried out with two kinds of synthesized nanomaterials, and discussed their adsorption effects of Pb (II). The characteristic was analyzed by SEM, XRD, XPS and magnetic measurements. As the results showeed, the particles size of the material became smaller, but the morphology did not change after adsorption. The change of Ms was from 42.7 and 62.0?emu/g to 25.6 and 89.4?emu/g, respectively. By Langmuir and Freundlich models, the maximum adsorption amounts of Pb (II) were 23.40 and 41.56?mg/g, respectively, and analysis demonstrated that the adsorption of Pb (II) on samples was monolayer adsorption. The kinetic analysis showed that the adsorption of Pb (II) on the two materials was more in accordance with the pseudo-second-order model, which indicated that adsorption process of the materials for Pb (II) were primarily limited by the chemical adsorption.     

气控环形防喷器密封胶芯大变形分析

针对气控环形防喷器胶芯在密封过程中的大变形以及与油管存在密封压力难以计算的问题,建立胶芯物理模型,结合厚壁筒理论与橡胶本构方程,同时考虑胶芯的材料非线性和几何非线性,探讨防喷器密封过程中胶芯变形与接触压力的变化。根据胶芯变形过程中无变形阶段、自由变形阶段和接触变形阶段的不同受力状况,利用迭代的方法对每个离散微段施加控制压力,得到不同控制压力下胶芯变形量与接触压力,并与仿真结果进行比较。结果表明:在自由变形阶段,随控制压力增加,胶芯变形量逐渐增大且由中间向两侧逐渐减小;在接触变形阶段,胶芯内径保持不变,且与油管间接触压力不断增加。采用胶芯变形理论方法计算的接触压力变化规律与仿真结果基本相同,验证了胶芯变形理论计算方法的正确性。     

Friction Behavior of Human Skin Rubbing against Different Textured Polymeric Materials Obtained by a 3D Printing Microfabrication Technique

Understanding friction behavior of human skin is indispensable in order to optimize surfaces and materials in contact with the skin. The coefficient of friction (COF) for different materials contacting against the skin is mainly influenced by the nature of the materials, mechanical contact parameters, and physiological skin conditions. The aim of the present research work was to study the grip effect of two different polymeric materials by producing different textured patterns using a 3D printing microfabrication technique and a replication technique. It was found that under the same contact conditions, a difference in the friction amplitude exists between the two different polymeric materials and that positive texturing, which consists of high relief or protrusions, showed higher COFs than negative texturing, consisting of low relief, holes, or dimples, which showed a decrease in friction as the textured pattern area density increased.     

Hierarchical Coherent Phonons in a Superatomic Semiconductor

The coupling of phonons to electrons and other phonons plays a defining role in material properties, such as charge and energy transport, light emission, and superconductivity. In atomic solids, phonons are delocalized over the 3D lattice, in contrast to molecular solids where localized vibrations dominate. Here, a hierarchical semiconductor that expands the phonon space by combining localized 0D modes with delocalized 2D and 3D modes is described. This material consists of superatomic building blocks (Re₆Se₈) covalently linked into 2D sheets that are stacked into a layered van der Waals lattice. Using transient reflectance spectroscopy, three types of coherent phonons are identified: localized 0D breathing modes of isolated superatom, 2D synchronized twisting of superatoms in layers, and 3D acoustic interlayer deformation. These phonons are coupled to the electronic degrees of freedom to varying extents. The presence of local phonon modes in an extended crystal opens the door to controlling material properties from hierarchical phonon engineering.     

Roles of calcium-containing alkali materials on dark fermentation and anaerobic digestion: A systematic review

The accelerated chemical-industry has caused a rapid increase of calcium-containing alkali wastes, containing a large amount of calcium, magnesium, aluminum, and iron ions and caused a great risk to environment. Anaerobic digestion or dark fermentation is one of the most promising technologies to recover biogas, such as methane and hydrogen. Nevertheless, the hydrolysis processes of lignocellulosic biomass and waste activated sludge were the rate-limiting step of the biochemical reactions, which focused on pretreatment to improve the biodegradability of substrate. In addition, when some easily acidified wastes, such as kitchen residue, fruit and vegetable waste, and high concentration organic wastewater, are used as substrate to produce hydrogen and methane, volatile fatty acid accumulation often occurs, causing the process instability. Thus, this paper reviewed the main roles of calcium-based alkali materials such as calcium oxide, calcium peroxide and calcium hydroxide on the substrate pretreatment for obtaining high biodegradability, while others (e.g. calcium carbonate, lime and red muds) used as additives for maintaining process stability, thereby increasing biogas yield from anaerobic digestion and dark fermentation.